WebRefractivity data for aluminosilicate glasses (densities and refractive indices) have been used to examine the relationship between oxygen polarisability, alpha (O2-), and optical basicity, and also to calculate the basicity moderating parameter of … WebThe concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses and melts and to account for the complexation of metal cations by a variety of anionic frameworks.
A New Sulfide Capacity Model for CaO-Al - Wiley Online Library
WebFeb 13, 2024 · However, whilst optical basicity can provide useful empirical correlations (e.g. sulphide capacity of ladle slags ), these values have not been successfully linked to … WebJan 1, 2024 · The optical basicity of prepared glasses decreased with the increasing concentration of lanthanum oxide. Metallization criterion on the basis of refractive index showed an increasing trend while energy band gap based metallization criterion showed a decreasing trend. coterie wedding
Oxide ion/electronic polarizability, optical basicity and linear ...
WebFinding a parameter of the same type for solid oxides was not so easy. Modern theories of reactivity propose to consider the oxidizing power, acidity, basicity, and reducing power, as steps along a same continuum, instead of distinct phenomena [3]. Among parameters, Zhang’s scale of electronegativity [4], optical electronegativity and optical ... WebApr 15, 2007 · This relationship presents a general trend toward an increase in the oxide ion polarizability with increase in optical basicity. The Λ values estimated from α O 2-using Eq. (6) are given in Table 1 (columns 9–10). Large α O 2-(n) values over 2 Å 3 and large Λ values over 1.0 are obtained. That is, the rare earth oxides showing electronic polarizability … For oxides, MO (M = Mg, Ca, Sr, Ba), the basicity moderating parameter of M gover… Arguments are presented justifying the use of fluoride optical basicity values (e.g… The optical basicity trend in alkali borate glasses has been studied in detail [2,13-… The basicity of the oxidic groups AlO 4 5−, SiO 4 4−, PO 4 3−, SO 4 2−, ClO 4 −, ca… The basicity of an oxide glass can be measured experimentally from the frequenc… breatharian deaths